塔里木盆地中秋1凝析气藏成藏条件及演化过程

2018年12月,塔里木盆地秋里塔格构造带天然气勘探取得重大突破,中秋1井在下白垩统巴什基奇克组测试获高产工业气流,发现了该构造带迄今为止最大的整装凝析气藏。为了给该构造带下一步油气勘探部署提供依据,在充分利用前人研究成果的基础上,基于岩心、薄片、测井及地球化学分析资料,明确了中秋1大型凝析气藏的油气藏特征和气藏类型,分析了该气藏天然气成藏条件并推演其演化过程。研究结果表明:①中秋1大型气藏属于低含凝析油凝析气藏,天然气为煤成气,主要来自区内侏罗系腐殖型煤系烃源岩;②该构造带能够形成大型油气藏的有利地质条件是三叠系和侏罗系发育的两套巨厚高演化烃源岩、白垩系发育的大型辫状河三角洲规模有效砂岩储层、喜马拉雅晚期以来的构造活动形成的大规模楔状叠瓦构造圈闭、古近系和新近系巨厚膏盐岩形成的优越保存条件,以及油气生成与圈闭形成的良好时空匹配;③该气藏具有先油后气、晚期快速气侵聚集成藏的成藏模式,总体上是一个"早期聚油、晚期气侵、改造调整、快速成藏"的成藏过程。结论认为,该构造带油气成藏条件优越,具有广阔的油气勘探前景。     

An efficient NFEM for optimal control problems governed by a bilinear state equation

In this paper, a nonconforming finite element method (NFEM) is proposed for the constrained optimal control problems (OCPs) governed by a bilinear state equation. The state and adjoint state are approximated by the nonconforming $E{Q}_1^{rot}$ element, and the control is approximated by the orthogonal projection through the state and adjoint state. Some superclose and superconvergence properties are obtained by full use of the distinguish characters of this $E{Q}_1^{rot}$ element, such as the interpolation operator equals the Ritz projection, and the consistency error is one order higher than its interpolation error in the broken energy norm. Finally, some numerical results are provided to verify the theoretical analysis.     

Adaptive neural network command filtered backstepping control of pure‐feedback systems in presence of full state constraints

An adaptive neural network (NN) command filtered backstepping control is proposed for the pure‐feedback system subjected to time‐varying output/stated constraints. By introducing a one‐to‐one nonlinear mapping, the obstacle caused by full stated constraints is conquered. The adaptive control law is constructed by command filtered backstepping technology and radial basis function NNs, where only one learning parameter needs to be updated online. The stability analysis via nonlinear small‐gain theorem shows that all the signals in closed‐loop system are semiglobal uniformly ultimately bounded. The simulation examples demonstrate the effectiveness of the proposed control scheme.     

多分量数据全波形反演在气藏检测中的关键问题——以苏里格气田为例

苏里格气田是中国典型的致密砂岩气藏，构造简单、平缓，横向非均质性强，有效储层与围岩声学特征差别小，地震响应不明显，常规地震监测方法预测难度大，但气田含气砂岩泊松比低，是地震气藏检测的有效参数。利用弹性全波形反演精度高和能处理复杂非均质介质的优势，反演地层拉梅常数、剪切模量和密度，并计算泊松比，从而进行气藏预测。重点阐述了苏里格气田多分量数据全波形反演初始模型建模、先验模型建模和地震数据预处理3个关键问题的处理方法。二维三分量数据反演和"甜点"预测结果表明：①对于具有强非均质性的苏里格气田，利用全波形反演获得精度较高的地层弹性参数能显著提高气藏预测的准确度；②苏里格地区构造简单、平缓，利用常规叠加速度并结合构造解释可以建立比较好的初始模型，从而有效地解决了周波跳跃和局部极小的难题；③先验知识的约束和地震数据的预处理是全波形反演成功应用于苏里格气田气藏检测的关键。     

Ab initio calculations of the NO2 fission for CL-20 conformers

NO₂ fission is regarded to be the most important initial decomposition process of 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaazaisowurtzitane (CL-20). In this study, four CL-20 conformers based on the ε-CL-20 were obtained after the optimization at m062x/cc-pvtz level, and the bond length, bond order and bond dissociation energy of the N-N bonds were examined to investigate the stability of these bonds. In addition, the rate constants and activation energy of the NO₂ fission were evaluated using the microcanonical variational transition state theory (μVT). The calculation results have shown that N-N bonds in the case of pseudo-equatorial and axial of nitro groups are the most stable and the least stable, respectively, by evaluating the bond length, bond order and minimum energy path (MEP). The NO₂ fission rate constants are affected by not only the stability of N-N bonds but also the repulsion forces from the other nitro groups, and the fission process for pseudo-equatorial positioning of nitro groups is easier to be accelerated due to the increase of the repulsion forces. The decomposition of CL-20 conformer may mainly originate from the fission of the pseudo-equatorial positioning of nitro groups, especially for CL-20 III conformer because of the significant low activation energy.     

On one boundary problem for nonlinear stationary controlled system

The object of study is nonlinear stationary controlled system of ordinary differential equations with constant disturbance in the right part. The problem of constructing the synthesising control function providing the transfer of this system from the initial state to the origin is considered. The sufficiently simple for numerical implementation algorithm of solution of the above-mentioned problem is obtained. It is shown that for local null controllability of the considered system, it is sufficient that the conditions of the Kalman's type were satisfied. In addition, the estimates restricting the choice of initial conditions and external disturbances under which the transfer is guaranteed are obtained. The main idea of the method of construction of the desired control function consists in reducing the original problem to stabilisation of a special kind linear non-stationary system and solving the Cauchy problem for an auxiliary system of ordinary differential equations closed by stabilising control. The simplicity of the realisation of this algorithm is determined by the construction of the auxiliary system and its stabilisation that could be obtained by analytical methods. The effectiveness of the method is illustrated by solving the problem of crane control and its numerical simulation.     

云南镇源难处理金精矿工艺矿物学研究

利用X射线衍射、X射线荧光光谱（XRF）、X射线能谱分析（EDX）和矿物解离分析（MLA）等检测手段对云南镇源难处理金精矿的化学组成、矿物组成、硫化物特征以及金的分布情况进行了详细的工艺矿物学研究。结果显示：该金矿以硫化矿、碳酸盐和硅酸盐类矿物为主，含有3.18%的有机碳和2.37%的无机碳。通过金的诊断浸出发现96.16%的金被硫化物包裹，少量金以单体形式存在。通过对主要载金矿物黄铁矿、辉锑矿和毒砂的粒度、包裹及裸露情况进行分析，得出大部分硫化矿以解离单体的形式存在，少部分与其他矿物共生。根据MLA测试及金的诊断浸出，认为大部分金被硫化矿完全包裹，处理该矿石时应先进行硫化物包裹层的氧化处理，再进行金矿的浸出。     

Psychrophilic hydrogen production from petrochemical wastewater via anaerobic sequencing batch reactor: techno-economic assessment and kinetic modelling

Independent hydrogen production from petrochemical wastewater containing mono-ethylene glycol (MEG) via anaerobic sequencing batch reactor (ASBR) was extensively assessed under psychrophilic conditions (15–25 °C). A lab-scale ASBR was operated at pH of 5.50, and different organic loading rates (OLR) of 1.00, 1.67, 2.67, and 4.00 gCOD/L/d. The hydrogen yield (HY) progressed from 134.32 ± 10.79 to 189.09 ± 22.35 mL/gMEG_initial at increasing OLR from 1.00 to 4.00 gCOD/L/d. The maximum hydrogen content of 47.44 ± 3.60% was achieved at OLR of 4.0 gCOD/L/d, while methane content remained low (17.76 ± 1.27% at OLR of 1.0 gCOD/L/d). Kinetic studies using four different mathematical models were conducted to describe the ASBR performance. Furthermore, two batch-mode experiments were performed to optimize the nitrogen supplementation as a nutrient (C/N ratio), and assess the impact of salinity (as gNaCl/L) on hydrogen production. HY substantially dropped from 62.77 ± 4.09 to 6.02 ± 0.39 mL/gMEG_initial when C/N ratio was increased from 28.5 to 114.0. Besides, the results revealed that salinity up to 10.0 gNaCl/L has a relatively low inhibitory impact on hydrogen production. Eventually, the cost/benefit analysis showed that environmental and energy recovery revenues from ASBR were optimized at OLR of 4.0 gCOD/L/d (payback period of 7.13 yrs).     

固体自拉曼激光器多波长输出研究

实验对比了a切和c切的Nd∶YVO4晶体作为激光晶体时,激光器输出光光谱及输出功率上的区别。设计了一种小型化固体自拉曼多波长激光器,实验证明通过调节倍频晶体BBO的角度,可实现多波长选择性输出及同时输出,并测量了其输出光谱及单波长输出时的功率。     

Production of hydrogen from methanol steam reforming using CuPd/ZrO2 catalysts – Influence of the catalytic surface on methanol conversion and CO selectivity

Electricity generation for mobile applications by proton exchange membrane fuel cells (PEMFCs) is typically hindered by the low volumetric energy density of hydrogen. Nevertheless, nearly pure hydrogen can be generated in-situ from methanol steam reforming (MSR), with Cu-based catalysts being the most common MSR catalysts. Cu-based catalysts display high catalytic performance, even at low temperatures (ca. 250 °C), but are easily deactivated. On the other hand, Pd-based catalysts are very stable but show poor MSR selectivity, producing high concentrations of CO as by-product. This work studies bimetallic catalysts where Cu was added as a promoter to increase MSR selectivity of Pd. Specifically, the surface composition was tuned by different sequences of Cu and Pd impregnation on a monoclinic ZrO₂ support. Both methanol conversion and MSR selectivity were higher for the catalyst with a CuPd-rich surface compared to the catalyst with a Pd-rich surface. Characterization analysis indicate that the higher MSR selectivity results from a strong interaction between the two metals when Pd is impregnated first (likely an alloy). This sequence also resulted in better metallic dispersion on the support, leading to higher methanol conversion. A H₂ production rate of 86.3 mmol h^?1 g^?1 was achieved at low temperature (220 °C) for the best performing catalyst.